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Oggetto:

Carbanion Chemistry in Organic Synthesis

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New Concepts in Chemical Synthesis and Reactivity

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Academic year 2021/2022

Teacher
Prof. Vittorio Pace (Titolare del corso)
Teaching period
To be defined
Type
Elective
Credits/Recognition
2 CFU
Course disciplinary sector (SSD)
CHIM/06 - organic chemistry
Delivery
Formal authority
Language
Italian
Attendance
Obligatory
Oggetto:

Sommario del corso

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Course objectives

The main objective of the lecture is illustrating synthetic strategies for generating new carbon-carbon
bonds through electrophilic-nucleophilic reactivity logics. In particular, the modulation of the reactivity of
(nucleophilic) carbanionic species conferred by the competent metal will be considered, in conjunction with
the stability and the (stereo)chemical integrity. Analogously, the chemical essence of the electrophiles will
be investigated.

The whole course follows an historical perspective, documenting how the conceptual
validation of reactivity principles introduced during the years continues to constitute a robust source of
inspiration for developing new chemical reactions. Through a complementary approach, the enabling of the
reactivity of notoriously elusive systems towards carbanions will be discussed.

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Course delivery

Aula Diagonale c/o Dip. Chimica

21.07.22 h 17-19

22.07.22 h 9-11

28.07.22 h 17-19

29.07.22 h 11-13

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Program

Carbanion chemistry.

Suggested readings and bibliography

Title:  
Handbook of Functionalized Organometallics: Applications in Synthesis
Year of publication:  
2005
Publisher:  
P. Knochel
Author:  
P. Knochel et al.
Required:  
No
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